Tetrahedron Letters p. 9601 - 9604 (1998)
Update date:2022-08-05
Topics:
Rainier, Jon D.
Allwein, Shawn P.
An iterative synthesis of fused ether ring systems has been developed. This strategy couples a cyclic enol ether oxidation and carbon-carbon bond forming reaction in one flask with an acid catalyzed cyclic acetal formation and alkoxide elimination in another flask. The result is a general and highly efficient two flask synthesis of fused ethers as are present in a wide variety of bioactive natural products.
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