A synthesis of the ring system of terpestacin

DOI: 10.1016/S0040-4039(98)02535-0

Source and publish data:

Tetrahedron Letters p. 843 - 846 (1999)

Update date:2022-08-03

Topics:

Authors:

Mermet-Mouttet, Marie-Paule

Gabriel, Kiroubagaranne

Heissler, Denis

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Article abstract of DOI:10.1016/S0040-4039(98)02535-0

The ring system of the sesterterpene terpestacin has been obtained from a cyclopentanic precursor prepared from endo-3-bromocamphor and from an acyclic keto phosphonate prepared from 6-methylhept-5-en-2-one. The connection of both compounds has been achieved by a Horner-Wadsworth-Emmons reaction on the one hand and by a McMurry reaction on the other.

Full text of DOI:10.1016/S0040-4039(98)02535-0

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