Tetrahedron Letters p. 843 - 846 (1999)
Update date:2022-08-03
Topics:
Mermet-Mouttet, Marie-Paule
Gabriel, Kiroubagaranne
Heissler, Denis
The ring system of the sesterterpene terpestacin has been obtained from a cyclopentanic precursor prepared from endo-3-bromocamphor and from an acyclic keto phosphonate prepared from 6-methylhept-5-en-2-one. The connection of both compounds has been achieved by a Horner-Wadsworth-Emmons reaction on the one hand and by a McMurry reaction on the other.
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