Tetrahedron Letters p. 25 - 28 (1999)
Update date:2022-08-03
Topics:
Nelson, Derek W.
Easley, Regina A.
Pintea, Beniamin N. V.
New methods for perfluoroalkylation of carbon-nitrogen double bonds have been developed. Addition of (trifluoromethyl)trimethylsilane (TMSCF3) to α,N-diarylnitrones produced α series of α-(trifluoromethyl)-N hydroxyl amines protected as their O-trimethylsilyl derivatives. An alternate procedure using pentafluoroethyllithium (F5C2L1) and chlorotrimethylsilane (TMSCI) afforded O-trimethylsilyl-α-(pentafluoroethyl)-N-hydroxyl amines.
View MoreNINGBO PANGS CHEM INT’L CO., LTD.
Contact:+86-0574-27666801
Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Contact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Shandong Wanda Organosilicon New Material Co., Ltd
Contact:+86-21-54177116;54302881
Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Ceresking Ecology & Technology co.,ltd
Contact:86 22 66218397
Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Doi:10.1021/ja00110a003
(1995)Doi:10.1016/j.tetlet.2018.07.032
(2018)Doi:10.1021/jo00298a024
(1990)Doi:10.1002/hlca.19500330627
(1950)Doi:10.1002/hlca.200390258
(2003)Doi:10.1021/ic980282s
(1999)
