Tetrahedron Letters p. 25 - 28 (1999)
Update date:2022-08-03
Topics:
Nelson, Derek W.
Easley, Regina A.
Pintea, Beniamin N. V.
New methods for perfluoroalkylation of carbon-nitrogen double bonds have been developed. Addition of (trifluoromethyl)trimethylsilane (TMSCF3) to α,N-diarylnitrones produced α series of α-(trifluoromethyl)-N hydroxyl amines protected as their O-trimethylsilyl derivatives. An alternate procedure using pentafluoroethyllithium (F5C2L1) and chlorotrimethylsilane (TMSCI) afforded O-trimethylsilyl-α-(pentafluoroethyl)-N-hydroxyl amines.
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(1999)
