Tetrahedron p. 3219 - 3232 (1999)
Update date:2022-08-05
Topics:
Ahmed, Mahmood
Barrett, Anthony G. M.
Beall, Jennifer C.
Braddock, D. Christopher
Flack, Kevin
Gibson, Vernon C.
Procopiou, Panayiotis A.
Salter, Matthew M.
Molybdenum carbene 6 catalyzed ring closing metathesis of (alkenyl)silyl ethers of homochiral allylic alcohols to afford 1,2-oxasilines which were elaborated in situ to give (E)-4-alkyl-1,2-disubstituted 3-buten-1-ol and (Z)-4-alkyl-4-silyl-1,2-disubstituted 3-buten-1-ol derivatives as single geometric isomers.
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