Selective N-N and W-N bond cleavage of tungsten pyrrolylimido complexes derived from tungsten dinitrogen complex

DOI: 10.1246/bcsj.72.425

Source and publish data:

Bulletin of the Chemical Society of Japan p. 425 - 432 (1999)

Update date:2022-08-04

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Authors:

Sasagawa, Takao

Seino, Hidetake

Ishii, Youichi

Mizobe, Yasushi

Hidai, Masanobu

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Article abstract of DOI:10.1246/bcsj.72.425

Treatment of the pyrrolylimido complexes cis,trans- [WX₂(NNCH=CHCH=CH)(L)(PMe₂Ph)₂] (X = Cl, Br, I; L = PMe₂Ph (6), CNBu¹, CO, PhC=CH, PhCHO, Br) with LiAlH₄ or KOH produced pyrrole, 1-amin

Full text of DOI:10.1246/bcsj.72.425

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Product name:cis,trans-[WCl₂(NNCH=CHCH=CH)(PhC_.tplbond.CH)(PMe₂Ph)2]

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