Acta Crystallographica, Section C: Crystal Structure Communications p. 508 - 510 (1999)
Update date:2022-08-04
Topics:
Tatar, Leyla
Uelkue, Dincer
Atakol, Orhan
In the title compounds, bis[2-(3-nitrophenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C13H9N2O3)2], and bis[2-(3-methoxyphenylnitrilomethylidyne)phenolato-N,O]zinc(II), [Zn(C14H12NO2)2], the tricilinic unit cell contains two inversion-related molecules. In both compounds, the Zn atom is in a slightly distorted tetrahedral coordination involving O and N atoms of two bidentate ligands. The dihedral angle defined by the two chelate rings is 98.09 (4)° for the methoxyphenyl complex and 98.05 (7)° for the nitrophenyl complex. The molecules are crosslinked via intermolecular hydrogen bonds.
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Doi:10.1002/hlca.19690520514
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(2000)Doi:10.1016/S0277-5387(98)00362-3
(1999)Doi:10.1016/S0040-4020(99)00274-4
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(2019)Doi:10.1246/bcsj.56.2537
(1983)
