Bulletin of the Chemical Society of Japan p. 2537 - 2538 (1983)
Update date:2022-08-04
Topics:
Ikehira, Hideyuki
Tanimoto, Shigeo
Oida, Tatsuo
The reaction of 1,3-dithiolane derivatives of ketones having a-hydrogen with lithium diisopropylamide results in fragmentation to the corresponding thioketone followed by further conversion in a few steps to the other intermediate species which, on trapping with alkyl halide, leads to a vinylic sulfide and/or a sulfide bearing a secondary alkyl group.
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