Studies on the total synthesis of the saponaceolides. 1. Enantioselective synthesis of the spiroketal subunit

DOI: 10.1016/S0040-4039(99)00366-4

Source and publish data:

Tetrahedron Letters p. 3063 - 3066 (1999)

Update date:2022-08-03

Topics:

Authors:

Vidari, Giovanni

Lanfranchi, Gianluigi

Pazzi, Natalina

Serra, Stefano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(99)00366-4

An asymmetric synthesis of the tricyclic Spiroketal subunit of the saponaceolides is described in which the absolute stereochemistry at C-2' and C-6' is established through a conformationally and stereoelectronically controlled cyclization of a dihydroxyk

Full text of DOI:10.1016/S0040-4039(99)00366-4

Products guided by the article

Product name:C₂₁H₃₀O₇S

Cas No:226927-03-3

R&D Labs maybe for 226927-03-3

Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City
Guarson Chemical Co., Ltd.

website:http://www.guarson.com

Contact:+86-523-88059600,+86-13805268803

Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China

Relevant to this article

Carbasaccharides via ring-closing alkene metathesis. A synthesis of (+)- valienamine from D-glucose

Doi:10.1002/(SICI)1522-2675(19990505)82:5<645::AID-HLCA645>3.0.CO;2-K
(1999)
Reactions of rhodium(II) and iridium(III) complexes bearing a P,O-coordination with tetracyanoethylene in the presence of KPF₆

Doi:10.1016/j.ica.2004.04.014
(2004)
REDOX TRANSFORMATIONS OF 2-FORMYLQUINOXALINE HYDRATE AND DIETHYLACETAL N,N'-DIOXIDES

Doi:10.1007/BF00513172
(1980)
Coupling reactions of ortho-substituted halobenzenes with alkynes. The synthesis of phenylacetylenes and symmetrical or unsymmetrical 1,2-diphenylacetylenes

Doi:10.1135/cccc19990649
(1999)
Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: Synthesis of enantiomerically enriched vicinal and geminal borosilanes

Doi:10.1002/chem.201203803
(2013)
Practical and efficient synthesis of α-Aminophosphonic acids containing 1,2,3,4-Tetrahydroquinoline or 1,2,3,4-Tetrahydroisoquinoline heterocycles

Doi:10.3390/molecules21091140
(2016)

Article Doi