Rearrangement and radical mediated decarboxylation of trimethylsilyl benzoates using xenon difluoride

DOI: 10.1039/p19960000121

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 121 - 122 (1996)

Update date:2022-07-30

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Authors:

Nongkunsarn, Pakawan

Ramsden, Christopher A.

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Article abstract of DOI:10.1039/p19960000121

Treatment of trimethylsilyl benzoates 1 with xenon difluoride in CH₂Cl₂ or C₆F₆ results in a novel ester rearrangement and formation of aryl fluoroformates 2: rearrangement is not observed in MeCN solution in wh

Full text of DOI:10.1039/p19960000121

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