Journal of Organic Chemistry p. 2752 - 2758 (2020)
Update date:2022-09-26
Topics:
Fu, Duo
Dong, Jun
Du, Hongguang
Xu, Jiaxi
A phenyltrimethylammonium tribromide-mediated nucleophilic substitution/oxygen transformation reaction of benzyl halides with DMSO has been developed. In this transition-metal-free reaction, DMSO acts as not only a solvent but also a "S(O)Me" source, thus providing a convenient method for the efficient and direct synthesis of various benzyl methyl sulfoxides.
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