Acta Crystallographica, Section C: Crystal Structure Communications p. 219 - 221 (1998)
Update date:2022-08-05
Topics:
Pascu, Sofia
Silaghi-Dumitrescu, Luminita
Blake, Alexander J.
Li, Wan-Sheung
Haiduc, Ionel
Sowerby, D. Bryan
The title molecule, [AsCl2(C6H11)3], has a distorted trigonal-bipyramidal geometry with three equatorial cyclohexyl groups and axial Cl atoms. The As-C distances [1.990(2), 1.988(2) and 1.981(3) A] differ slightly, and the equatorial angles C-As-C are 117.35 (10), 117.60(10) and 123.26(8)°. The angle subtended at arsenic by the axial Cl atoms is 178.60(2)°, but the chlorine separation distances [2.4957 (7) and 2.3029 (7) A] differ substantially. The As atom lies out of the plane of the equatorial C atoms, suggesting a contribution from the ionic structure, [As(cyclo-C6H11)3]+.Cl-.
View MoreHubei Lingsheng Pharmaceuticals Co., Ltd.
Contact:+86-0710-3538058
Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Contact:+86-21-61318535
Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
website:https://www.finerchem.com
Contact:+86-531-88989536
Address:New Material Industrial Park, Jinan City, China
Contact:+86-371-55981030
Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Doi:10.1021/ol9907724
(1999)Doi:10.1016/S0960-894X(02)00884-3
(2003)Doi:10.1016/j.jorganchem.2008.03.001
(2008)Doi:10.1021/jm00295a006
(1970)Doi:10.3906/kim-1509-21
(2016)Doi:10.1039/jr9390000091
(1939)
