A novel stereoselective route to a fumagillin and ovalicin synthetic intermediate

DOI: 10.1016/S0040-4039(99)00912-0

Source and publish data:

Tetrahedron Letters p. 4797 - 4800 (1999)

Update date:2022-08-03

Topics:

Authors:

Picoul, Willy

Urchegui, Raquel

Haudrechy, Arnaud

Langlois, Yves

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(99)00912-0

A strategy using a highly stereoselective Claisen-Ireland rearrangement followed by a Grubbs metathesis afforded in a good overall yield after further functionalisation a potentially synthetic precursor of fumagillin and ovalicin.

Full text of DOI:10.1016/S0040-4039(99)00912-0

Products guided by the article

Product name:(E)-(2S,3S)-2-But-3-enyl-3-(tert-butyl-diphenyl-silanyloxymethyl)-2-(4-methoxy-benzyloxy)-hex-4-enoic acid methyl ester

Cas No:244260-84-2

R&D Labs maybe for 244260-84-2

GN chemicals co.,ltd

Contact:86 311 85902108 / 85902109

Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
Shanghai Dano Pharmaceutical Co.,Ld.(expird)

Contact:+86-592-6266840

Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China

Relevant to this article

Doi:10.1007/BF00500671
()
Doi:10.1002/etc.5620211022
(1935)
On the Reaction of Silanols with Alkoxysilanes

Doi:10.1002/prac.19963380172
(1996)
2-Deoxy-2-iodo- and 2-deoxy-2-bromo-α-glucopyranosyl trichloroacetimidates: Highly reactive and stereoselective donors for the synthesis of 2-deoxy-β-glycosides

Doi:10.1021/ol9908070
(1999)
Activation of H₂ by halocarbonyl bis-phosphine and bis-arsine iridium(I) complexes. The use of parahydrogen induced polarisation to detect species present at low concentration and investigate their reactivity

Doi:10.1039/b107444j
(2002)
Synthesis of several functionalized cis-diisocyanide and fac-triisocyanide metal complexes

Doi:10.1016/S0022-328X(99)00185-0
(1999)

Article Doi