Tetrahedron p. 9867 - 9880 (1999)
Update date:2022-09-26
Topics:
La Ferla, Barbara
Lay, Luigi
Guerrini, Marco
Poletti, Laura
Panza, Luigi
Russo, Giovanni
The chemical synthesis of disaccharides 1 and 2, useful building-blocks for the preparation of a new series of heparin related oligosaccharides containing the unusual sequence (GlcN-IdoA)(n), is described. In addition, the orthogonality of the protective groups would allow access to a wide array of differently sulfated oligosaccharides. As the simplest members of this new class of oligomer, the synthesis of sulfated disaccharides 3 and 4 fully deprotected is reported.
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