Preparative electrochemical oxidation of cyclic peralkylsilanes

DOI: 10.1016/S0040-4039(00)61166-8

Source and publish data:

Tetrahedron Letters p. 5633 - 5636 (1992)

Update date:2022-08-04

Topics:

Authors:

Becker Becker

Shakkour

West West

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Article abstract of DOI:10.1016/S0040-4039(00)61166-8

The electrochemical oxidation of cyclic peralkylsilanes undergo ring opening followed by further Si-Si bond cleavage and reaction with BF₄^- to form α,ω-difluorosilanes, F-(SiR₂)(n)-F, as major products.

Full text of DOI:10.1016/S0040-4039(00)61166-8

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