Highly efficient and selective displacement of alkylthio group on acylketene O,S-acetals by organocopper reagents: A novel route to 2-alkoxy/aryloxy-1-alkenylketones

DOI: 10.1016/0040-4039(95)01990-Y

Source and publish data:

Tetrahedron Letters p. 9377 - 9380 (1995)

Update date:2022-07-30

Topics:

Authors:

Mehta, Barun K.

Dhar, Sanchita

Ila Ila

Junjappa

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Article abstract of DOI:10.1016/0040-4039(95)01990-Y

Acylketene O,S-acetals 1a-k undergo efficient and selective conjugate displacement of alkylthio group with organocopper(I) reagents to afford the corresponding 6-alkoxy/aryloxy enones 2-21 in good yields.

Full text of DOI:10.1016/0040-4039(95)01990-Y

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