Tetrahedron Letters p. 6009 - 6012 (1990)
Update date:2022-08-03
Topics:
Nikolaides, Nicholas
Godfrey, Alexander G.
Ganem, Bruce
New chemistry is observed in the thermal rearrangement of N-alkyl-N-nitrosoamides 1 under highly nucleophilic, dissociating conditions. An apparent change in the mechanism of the rate-determining step is noted. In DMSO containing N-methylmorpholine-N-oxide, oxidative deamination of 10 via 11 and 12 (Eqn 3) to aldehydes occurs in good yield.
View MoreContact:(1) 206-3550089
Address:5115 NE 8TH PL, Renton, WA 98059 USA
Dalian Synco Chemical Co., Ltd.
Contact:+86-411-83635150
Address:Rm 1004, 24, Tangshan Street, Dalian
Xiamen Huasing Chemicals Co.Ltd.
Contact:0086-592-6228397
Address:NO.24, Xinglin North 2nd Road,Jimei district
Contact:+86-574-87065746
Address:10th Floor, No.787 Baizhang East Road,
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.
Contact:+86-417-2927806
Address:yingkou
Doi:10.1039/jr9650003706
(1965)Doi:10.3762/bjoc.12.43
(2016)Doi:10.1002/(SICI)1099-1344(199911)42:11<1039::AID-JLCR259>3.0.CO;2-1
(1999)Doi:10.1021/jm991110n
(1999)Doi:10.1016/S0957-4166(99)00353-5
(1999)Doi:10.1002/hlca.19710540619
(1971)
