Unusual stereochemical course of epoxide rearrangement in a carvone-derived series

DOI: 10.1016/S0040-4039(99)01623-8

Source and publish data:

Tetrahedron Letters p. 7969 - 7973 (1999)

Update date:2022-08-02

Topics:

Authors:

Neef, Guenter

Baesler, Siegfried

Depke, Gisbert

Vierhufe, Harry

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Article abstract of DOI:10.1016/S0040-4039(99)01623-8

Carvone-derived 2,3-epoxy alcohol derivatives rearrange with stereoselective formation of ring-contracted ketones. In contrast to previously described similar processes, the stereochemical result seems to be independent of epoxide configuration.

Full text of DOI:10.1016/S0040-4039(99)01623-8

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