Tetrahedron p. 13377 - 13394 (1999)
Update date:2022-08-02
Topics:
Lehmann, Matthias
Schartel, Bernhard
Hennecke, Manfred
Meier, Herbert
On the basis of Wittig-Homer reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers (2a-c, 2a'-c') which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units.
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