Preparation and cyclopropanation of selected oxapolycycles

DOI: 10.1016/S0040-4020(99)00824-8

Source and publish data:

Tetrahedron p. 13395 - 13406 (1999)

Update date:2022-08-05

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Authors:

Sander, Michael

Dehmlow, Eckehard Volker

Neumann, Beate

Stammler, Hans-Georg

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Article abstract of DOI:10.1016/S0040-4020(99)00824-8

The Diels-Alder reaction of dimethyl furandicarboxylate 6 with DMAD is investigated and the exo-exo bisadduct 8 is fully characterized. Monoadduct 7, 8, and test system 12 are cyclopropanated with diazomethane giving 10, 11, and 14. Then 7, 8, and 12 are

Full text of DOI:10.1016/S0040-4020(99)00824-8

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