Reaction of ?NO thiolate and thiol complexes: Elimination of PhSNO from W(phen)(CO)2(SPh)2, CO from W(phen)(CO)2((-S)2Arene), and HNO from W(phen)(CO)3(RSH)

DOI: 10.1021/ic990830h

Source and publish data:

Inorganic Chemistry p. 6212 - 6217 (1999)

Update date:2022-08-04

Topics:

Authors:

Capps, Kenneth B.

Bauer, Andreas

Abboud, Khalil A.

Hoff, Carl D.

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Article abstract of DOI:10.1021/ic990830h

Reaction of ?NO with W(phen)(CO)₂(SPh)₂ (phen = 1,10-phenanthroline) results in clean conversion to W(phen)-(CO)₂(NO)(SPh). Reduction of the W(II) bisthiolates to the W(0) nitrosyl thiolate occurs with simultaneous reducti

Full text of DOI:10.1021/ic990830h

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