Studies directed toward the synthesis of taxanes: Evaluation of the B- ring formation by an intramolecular nitrile oxide cycloaddition

DOI: 10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9

Source and publish data:

European Journal of Organic Chemistry p. 3241 - 3249 (1999)

Update date:2022-08-05

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Authors:

Nivlet, Alex

Dechoux, Luc

Martel, Jean-Philippe

Proess, Gottfried

Mannes, Dietrich

Alcaraz, Lilian

Harnett, Jerry J.

Le Gall, Thierry

Mioskowski, Charles

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Article abstract of DOI:10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9

Several models for the formation of the 8-membered B-ring of taxanes by an intramolecular nitrile oxide [3+2] cycloaddition were prepared from the monoacetal of 2,2-dimethylcyclohexane-1,3-dione (5). The nitrile oxides were then generated under high-dilut

Full text of DOI:10.1002/(SICI)1099-0690(199912)1999:12<3241::AID-EJOC3241>3.0.CO;2-9

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