Heterocyclization of tropinone oximes and 3-methyl-3-azabicyclo[3.3.1]-nonan-9-one with acetylene in a superbasic medium

DOI: 10.1007/BF02324648

Source and publish data:

Chemistry of Heterocyclic Compounds p. 613 - 616 (1999)

Update date:2022-08-04

Topics:

Authors:

Varlamov

Voskresenskii

Borisova

Chernyshev

Levov Levov

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Article abstract of DOI:10.1007/BF02324648

Tropinone oxime reacts with acetylene in superbasic medium to form ordinary products of heterocyclization. The oxime of 3-methyl-3-azabicyclo[3.3.1]nonan-9-one does not undergo heterocyclization due to the impossibility of a [3,3]-sigmatropic rearrangement of its vinyl ether. 1999 KluwerAcademic/Plenum Publishers.

Full text of DOI:10.1007/BF02324648

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