Journal of the Chemical Society. Chemical communications p. 763 - 764 (1981)
Update date:2022-08-03
Topics:
Jackson, Anthony H.
Jenkins, Rhiannydd M.
Jones, D. Michael
Matlin, Stephen A.
The γ-meso-hydroxy-derivative of protoporphyrin IX has been synthesised by condensation of a bis(formylpyrrolyl) ketone and a dipyrrolylmethane; the iron complex underwent oxidative ring-opening to give biliverdin IXγ (pterobiline), the blue-green butterfly pigment, thus providing a model for its biosynthesis.
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