RADICAL STABILIZING EFFECTS. A COMPARISON OF TRANSITION STATE EFFECTS (RATES OF AZOALKANE DECOMPOSITIONS) WITH CALCULATED (AB INITIO) PI SPIN DENSITIES

DOI: 10.1016/0040-4020(80)80070-6

Source and publish data:

Tetrahedron p. 1753 - 1756 (1980)

Update date:2022-08-04

Topics:

Authors:

Dube, Michael F.

Timberlake, Jack W.

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Article abstract of DOI:10.1016/0040-4020(80)80070-6

Rate studies on five azoalkanes (4a-e) have been studied to assess important radical stabilizing effects.MO calculations of spin densities for three radicals with pi systems are correlated with kinetic rates of radical formation.

Full text of DOI:10.1016/0040-4020(80)80070-6

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