(E)- and (Z)-(1-Iodo-1-alkenyl)silanes. Their Preparation and Their Conversion ino (E)- and (Z)-(1-Lithio-1-alkenyl)silanes

DOI: 10.1021/jo00320a013

Source and publish data:

Journal of Organic Chemistry p. 1292 - 1295 (1981)

Update date:2022-08-04

Topics: Conversion Preparation

Authors:

Zweifel, George

Murray, Rex E.

On, Harry P.

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Article abstract of DOI:10.1021/jo00320a013

(Z)-(1-Iodo-1-alkenyl)trimethylsilanes can be conveniently obtained by isomerization of the readily available E isomers through the intermediacy of (1-lithioalkenyl)silanes formed by addition of catalytic amounts of tert-butyllithium.Reaction of (E)- and

Full text of DOI:10.1021/jo00320a013

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