A new catalytic and enantioselective desymmetrization of symmetrical methylidene cycloalkene oxides

DOI: 10.1021/ol005584o

Source and publish data:

Organic Letters p. 933 - 936 (2000)

Update date:2022-07-30

Topics: Yield Enantioselective Enantiomeric excess Reaction Conditions Catalyst Loading Desymmetrization Catalytic

Authors:

Bertozzi, Fabio

Crotti, Paolo

Macchia, Franco

Pineschi, Mauro

Arnold, Alexander

Feringa, Ben L.

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Article abstract of DOI:10.1021/ol005584o

(equation presented) Chiral copper complexes of C₂-symmetrical phosphoroamidites were found to be highly effective catalysts for both kinetic resolution and novel desymmetrization reactions of new methylidene epoxycycloalkanes.

Full text of DOI:10.1021/ol005584o

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