Liebigs Annalen p. 1529 - 1532 (1996)
Update date:2022-08-02
Topics:
Morgenthaler, Jens
Ruechardt, Christoph
1,3-Cyclohexadiene, 1,3-cycloheptadiene and cycloheptatriene are smoothly hydrogenated to cyclohexene and cycloheptene, respectively, when heated to 260-340°C with an excess of 9,10-dihydroanthracene (DHA) in diphenyl ether or benzonitrile. On the basis of a mechanistic study a nonchain three-step mechanism is proposed which is initiated by a transfer of a hydrogen atom from DHA to the polyenes (retrodisproportionation). VCH Verlagsgesellschaft mbH, 1996.
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Doi:10.1016/0040-4039(95)02331-3
(1996)Doi:10.1111/j.1151-2916.2003.tb03514.x
(1859)Doi:10.1016/S0040-4039(00)00133-7
(2000)Doi:10.1021/jo9915574
(2000)Doi:10.1021/ol005643y
(2000)Doi:10.1021/ja020206v
(2002)
