Tetrahedron Letters p. 823 - 826 (1996)
Update date:2022-08-02
Topics:
Snelgrove, Darren W.
MacFaul, Philip A.
Ingold, Keith U.
Wayner, Danial D. M.
The oxidation of cyclooctane using tert-alkyl hydroperoxides under GoAggv conditions has been examined using selected alkyl hydroperoxides as mechanistic probes. The results indicate that the products are formed by alkoxyl radical-induced reactions, there being no need to invoke any chemistry involving high valent iron-oxo species.
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