Scholarly article on Benzenesulfonic acid, 3,3'-(1,2-ethenediyl)bis[6-amino- 2703-04-0 from Canadian Journal of Chemistry p. 1409 - 1417

DOI: 10.1139/v96-159

Source and publish data:

Canadian Journal of Chemistry p. 1409 - 1417 (1996)

Update date:2022-07-30

Topics:

Authors:

Martre, Anne-Marie

Mousset, Guy

Cosoveanu, Veronica

Danciu, Virginia

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1139/v96-159

This work concerns the electrochemical and chemical reductions of 4,4′-dinitrodibenzyl and 4,4′-dinitrostilbene 2,2″-disulfonic acid under various experimental conditions. On the one hand, the electrochemical reduction is realized on Sn, monel, and Hg electrodes with or without the presence of a redox couple, and on the other hand, the chemical reduction is performed by mean of an electrochemically generated reducing agent (Sn⁰). According to the type of redox couple used (Ti³⁺/Ti⁴⁺ or Sn⁰/Sn²⁺), important changes in the nature and the ratio of reaction products are observed. The best conditions for obtaining di- or monoamines are defined, they correspond to 90% yield for the diamines, 70% and 50%, respectively, for 4-amino-4′-nitrodibenzy land for 4-amino-4′-nitrostilbene-2,2′-disulfonic acid. The electrochemical behavior of the dinitro derivatives and of TiOSO₄, TiCl₄, and SnCl₂ used as precursors of the redox couples is studied under conditions of macroscale electrolyses (5 N H₂SO₄ - EtOH 50/50, 2.5 N H₂SO₄, and 10% HCl).

Full text of DOI:10.1139/v96-159

Products guided by the article

Product name:Benzenesulfonic acid, 3,3'-(1,2-ethenediyl)bis[6-amino-

Cas No:2703-04-0

R&D Labs maybe for 2703-04-0

ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Wuhan Biet Co., Ltd

website:http://www.biet.com.cn/

Contact:+86-27-8369 8488

Address:No. 6, Building 21, China Merchants Fanwang, Sixin North Road, Hanyang District, Wuhan City, Hubei Province
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province

Relevant to this article

Doi:10.1007/BF00471249
()
Doi:10.1007/BF00476810
()
Practical synthesis of a 1β-methylcarbapenem, J-111,225, using 4-mercapto-2-[4-(N-methylaminomethyl)phenyl]pyrrolidine as a precursor

Doi:10.1248/cpb.49.476
(2001)
Doi:10.1021/ja01298a017
(1936)
Electronic halocyclization and radical haloazidation of benzene-linked 1,7-dienes for the synthesis of functionalized 3,1-benzoxazines

Doi:10.1039/c6ob02566h
(2017)
Cycloaddition of acyclic conjugated dienes with a tetrachloro- substituted oxyallyl intermediate generated from pentachloroacetone

Doi:10.1002/1099-0690(200004)2000:7<1335::AID-EJOC1335>3.0.CO;2-2
(2000)

Article Doi

DOI: 10.1139/v96-159