Formation of 5,η1-C5H4C(OCOR)=C(OCOR)CO>Fe(CO)2 Complexes via Triple CO Insertion into Cyclopentadienyl Anions by Fe(CO)5

DOI: 10.1246/cl.1988.73

Source and publish data:

Chemistry Letters p. 73 - 76 (1988)

Update date:2022-08-05

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Authors:

Nakanishi, Saburo

Hirano, Takehiro

Otsuji, Yoshio

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Article abstract of DOI:10.1246/cl.1988.73

The reaction of cyclopentadienyl anions with Fe(CO)5 in the presence of acyl chlorides gave <η⁵,η¹-C5H4C(OCOR)=C(OCOR)CO>Fe(CO)5 complexes, accompaning a triple CO insertion into the anions and a double acylation.

Full text of DOI:10.1246/cl.1988.73

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