Chemical and Pharmaceutical Bulletin p. 855 - 860 (2000)
Update date:2022-08-03
Topics:
Matsushima, Tomohiro
Nakajima, Noriyuki
Zheng, Bao-Zhong
Yonemitsu, Osamu
A stereoselective synthesis is described of the 18-membered lactone (2) via an efficient macrolactonization of the conformation-controlled seco-acid (3); this was designed with the aid of molecular mechanics (MM)-calculation and synthesized by coupling between the C1 - C12 (4) and C13 - C23 (5) fragments.
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