
Phosphorus, Sulfur and Silicon and the Related Elements p. 235 - 243 (1999)
Update date:2022-07-30
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2-Amino-3(4,5-dihydro-1H-imidazol-2-yl)thieno[2,3-b]quinoxaline 2 was prepared and then allowed to react with nitrous acid, triethyl orthoformate, acetic anhydride and carbon disulfide to give the imidazotriazinothienoquinoxaline 3 and imidazopyrimidothienoquinoxaline 4-6 respectively. Starting with thione 6 a series of S-ubstituted mercapto derivatives 7-10 was obtained. Reaction of 2-amino-3-carbonitrile-thieno[2,3-b]quinoxaline 1 with acrylonitrile, malononitrile and/or arylidine malononitrile gave pyridothienoquinoxaline derivatives 11-13.
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