Dianionic amidinates at silicon and germanium centers: Four-, six- and eight-membered rings

DOI: 10.1016/j.jorganchem.2007.02.032

Source and publish data:

Journal of Organometallic Chemistry p. 2789 - 2799 (2007)

Update date:2022-08-04

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Authors:

Segmüller, Thomas

Schlüter, Peter A.

Drees, Markus

Schier, Annette

Nogai, Stefan

Mitzel, Norbert W.

Stra?ner, Thomas

Karsch, Hans H.

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Article abstract of DOI:10.1016/j.jorganchem.2007.02.032

At variance to an earlier finding, the reaction of Me₂SiCl₂ with Li[(Me)N-C(Ph)-NH] (1a), in the presence of a base, gives a six-membered ring molecule μ-[(Ph)(MeN)C-N][-SiMe₂-N-C(Ph)-N(Ph)-SiMe₂-] (s3a), wherea

Full text of DOI:10.1016/j.jorganchem.2007.02.032

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