Journal of Organometallic Chemistry p. 313 - 322 (1985)
Update date:2022-08-04
Topics:
Chen, Grace J.
Tamborsky, Christ
Perfluoroalkyl ether substituted silicon compounds of the type (CH3)nSi(RfORf)4-n (n=1-3) and HSi(RfORf)3 where RfORf=F(CF3)2COCF2CF2have been synthesized in good yields (64-81percent) through the reaction between the organolithium reagent RfORfLi and the corresponding silicon chloride.The stability of these compounds towards acid, base and aqueous media were studied and the ease of cleavage of the Si-RfORf bond was found to be in the order HSi(RfORf)3>CH3Si(RfORf)3>(CH3)2Si(RfORf)2>(CH3)3SiRfORf.The influence of the RfORf group on some properties of these compounds is also described.
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