DARSTELLUNG UNG METALLAUSTAUSCH DER CLUSTER (RGe)2Co4(CO)11

Article abstract of DOI:10.1016/0022-328X(83)85178-X

The reaction of RGeHal3 (R = Me, t-Bu, Ph) with KCo(CO)4 yields the trinuclear clusters RGeCo3(CO)9 and in the case of R = t-Bu or Ph the tetranuclear clusters (RGe)2Co4(CO)11.Under CO the yield of (RGe)2Co4(CO)11 is increased.In (t-BuGe)2Co4(CO)11 metal