
Tetrahedron Letters p. 2435 - 2436 (1995)
Update date:2022-08-04
Topics:
Hanusa, Timothy P.
The previously reported reaction of phenylcalcium iodide with N2O in ether to form products with aryl-N bonds has been reexamined with various solvents and methylated aryliodides. The yield of azobenzene is maximized using DME as the solvent, and the insertion reactions may involve diorganocalcium (Ar2Ca) intermediates.
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