Stereoselective total synthesis of (-)-synrotolide diacetate from d-ribose

DOI: 10.1016/j.tet.2007.03.011

Source and publish data:

Tetrahedron p. 3995 - 3999 (2007)

Update date:2022-08-04

Topics: Stereoselective synthesis Total synthesis D-ribose Carbon-carbon bond formation Retrosynthetic analysis Purification and characterization Final steps Elaboration Repetition and Optimization Ester Formation Isolation and Analysis

Authors:

Krishna, Palakodety Radha

Reddy, P. Srinivas

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Article abstract of DOI:10.1016/j.tet.2007.03.011

Stereoselective total synthesis of synrotolide as its diacetate from d-ribose utilizing a diastereoselective Grignard reaction, preferential (Z)-Wittig olefination, asymmetric allylation, and ring closing metathesis as key steps is reported.

Full text of DOI:10.1016/j.tet.2007.03.011

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