Tetrahedron p. 4981 - 4986 (1984)
Update date:2022-08-03
Topics:
Iijima, Hiroyuki
Endo, Yasuyuki
Shudo, Koichi
Okamoto, Toshihiko
The acid-catalyzed solvolysis of N-tosyl-O-arylhydroxylamines in aromatic solvents and the thermolysis of N-aryloxypyridinium salts involve common intermediates, phenoxenium ions, for the formation of hydroxybiphenyl derivatives.Diphenylethers are formed when the heterolysis of the N-O bonds is slow and the aromatic solvent has high nucleophilicity.
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