Convenient method for the reduction of the double-bond of cyclic vinylphosphine oxides using borane

Article abstract of DOI:10.1080/00397910008087043

The electronpoor double-bond of cyclic vinylphosphine oxides (1, 3 and 4) is easily reduced by borane in a selective manner to give the corresponding saturated derivatives (2, 4 and 5, respectively) Under forcing conditions, change of the functionality may also take place.

Full text of DOI:10.1080/00397910008087043

This article was downloaded by: [Virginia Tech Libraries]
On: 19 October 2014, At: 00:31
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Convenient Method for the
Reduction of the Double-
Bond of Cyclic Vinylphosphine
Oxides Using Borane
Gy. Keglevich a , M. Fekete a , T. Chuluunbaatar a ,
A. Dobó b , Zs. Böcskei c & L. Töke a
a Technical University of Budapest, Department of
Organic Chemical Technology , 1521, Budapest,
Hungary
b Hungarian Academy of Sciences, Chemical
Research Center , 1525, Budapest, Hungary
c Chinoin Pharmaceuticals , 1045, Budapest, Hungary
Published online: 04 Dec 2007.
To cite this article: Gy. Keglevich , M. Fekete , T. Chuluunbaatar , A. Dobó , Zs.
Böcskei & L. Töke (2000) Convenient Method for the Reduction of the Double-
Bond of Cyclic Vinylphosphine Oxides Using Borane, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 30:23,
4221-4231, DOI: 10.1080/00397910008087043
To link to this article: http://dx.doi.org/10.1080/00397910008087043
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.

However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions