Zeitschrift fur Anorganische und Allgemeine Chemie p. 1263 - 1268 (1996)
Update date:2022-08-03
Topics:
Biehl, Alexander
Boese, Roland
Haas, Alois
Klare, Christiane
Peach, Michael
The crystal structure of (C6F5S)3N has been examined. The compounds (C6F5S)2NX, X = SiMe3 and 1/2Hg have been prepared from (C6F5S)2NH and characterised. In a number of other reactions, such as oxidation and irradiation, the S-N bond in (C6F5S)2NH was readily fractured, forming the disulfide, (C6F5S)2. The compound (C6F5S)3N has been found to be unreactive. Details of the mass and 13C NMR spectra of (C6F5S)nNH3-n, n = 1, 2, 3 are reported. Johann Ambrosius Barth 1996.
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