Reactions of pentafluorobenzenesulfanylamines (C6F5S)nNH3-n, n = 1, 2, 3 and the structure of (C6F5S)3N

Article abstract of DOI:10.1002/zaac.19966220726

The crystal structure of (C₆F₅S)₃N has been examined. The compounds (C₆F₅S)₂NX, X = SiMe₃ and 1/2Hg have been prepared from (C₆F₅S)₂NH and characterised. In a number of other reactions, such as oxidation and irradiation, the S-N bond in (C₆F₅S)₂NH was readily fractured, forming the disulfide, (C₆F₅S)₂. The compound (C₆F₅S)₃N has been found to be unreactive. Details of the mass and ¹³C NMR spectra of (C₆F₅S)_nNH_3-n, n = 1, 2, 3 are reported. Johann Ambrosius Barth 1996.