Tetrahedron Letters p. 8479 - 8483 (2000)
Update date:2022-08-03
Topics:
Goto
Hino
Kawashima
Kaminaga
Yano
Yamamoto
Takagi
Nagase
The molecular structure of a stable S-nitrosothiol bearing a novel trityl-type steric protection group was established by X-ray crystallographic analysis together with that of the corresponding S-nitrothiol. It was found that the S-nitrosothiol exists as a mixture of the syn and anti isomers with respect to the C-S-N-O linkage in the crystalline state, in agreement with the theoretical calculation on Ph3CSNO. (C) 2000 Elsevier Science Ltd.
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