Synthesis and Stereochemistry of Tetra-o-tolylethene and 1,1,2,2-Tetra-o-tolylethane

DOI: 10.1021/jo00159a021

Source and publish data:

Journal of Organic Chemistry p. 1890 - 1898 (1983)

Update date:2022-07-29

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Authors:

Willem, Rudolph

Pepermans, Henri

Hallenga, Klaas

Gielen, Marcel

Dams, Rudy

Geise, Herman J.

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Article abstract of DOI:10.1021/jo00159a021

The synthesis of tetra-o-tolylethene and 1,1,2,2-tetra-o-tolylethane through reductive coupling of di-o-tolyl ketone by TiCl3/LiAlH4 in THF is described.The 1H NMR spectra of tetra-o-tolylethene display several coalescences between -90 and 60 degC.Evidenc

Full text of DOI:10.1021/jo00159a021

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