Journal of the American Chemical Society p. 906 - 910 (1989)
Update date:2022-08-05
Topics:
Sugie, Masaaki
Takeo, Harutoshi
Matsumura, Chi
The microwave spectrum of N-chloromethylenimine and 1-azetine has been observed following pyrolysis and dehydrochlorination of N-chloroazetidine, respectively.In addition, pyrolysis of 1-azetine gives another unstable molecule, 2-azabutadiene.The rotational constants determined are A=62434.90(10), B=6676.389(13), and C=6022.843(11) MHz for N-chloromethylenimine, A=62344.73(11), B=6531.700(13), and C=5904.017(11) MHz for the 37Cl species of N-chloromethylenimine, A=13911.630(24), B=12713.799(24), and C=7254.990(24) MHz for 1-azetine, and A=47186.010(23),B=4886.5325(27), and C=4430.0673(23) MHz for 2-azabutadiene.The dipole moments and nuclear quadrupole coupling constants have also been determined from analysis of the spectra.The molecular constants estimated by ab initio MO calculations have been found to be consistent with the experimental results.
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