Stereochemistry of Nucleophilic Reductions of 2-Methyl-4-t-butylcyclohexanones. Further Support for the Linear Combination of SSC and PSC Stereochemical Models

DOI: 10.1039/P29890000747

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Journal of the Chemical Society. Perkin transactions II p. 747 - 750 (1989)

Update date:2022-08-04

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Authors:

Fang, Jim-Min

Sun, Shih-Feng

Rei, Min-Hon

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Article abstract of DOI:10.1039/P29890000747

trans-2-Methyl-4-t-butylcyclohexanone reacts with lithium aluminum hydride, lithium trimethoxyaluminium hydride and methyl-lithium with equal stereoselectivity of axial attack (i. e. 95 +/- 1 percent).This is attributed to the equal steric strain control

Full text of DOI:10.1039/P29890000747

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