A novel modification of the Ritter reaction using trimethylsilyl cyanide

DOI: 10.1016/0040-4039(96)01890-4

Source and publish data:

Tetrahedron Letters p. 8129 - 8132 (1996)

Update date:2022-08-03

Topics:

Authors:

Chen Chen

Goel Goel

Kesten Kesten

Knobelsdorf

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Article abstract of DOI:10.1016/0040-4039(96)01890-4

A new modification of the Ritter reaction using trimethylsilyl cyanide (Me₃SiCN) is described, which converts alcohols to their corresponding formamides in high yields using a convenient procedure. The reaction conditions and mechanism are discussed. In some cases, new formamides are synthesized which cannot be prepared by the classical Ritter reaction.

Full text of DOI:10.1016/0040-4039(96)01890-4

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