Tetrahedron Letters p. 8129 - 8132 (1996)
Update date:2022-08-03
Topics:
Chen
Goel
Kesten
Knobelsdorf
A new modification of the Ritter reaction using trimethylsilyl cyanide (Me3SiCN) is described, which converts alcohols to their corresponding formamides in high yields using a convenient procedure. The reaction conditions and mechanism are discussed. In some cases, new formamides are synthesized which cannot be prepared by the classical Ritter reaction.
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