Fluorocyclization of N-Propargylamides to Oxazoles by Electrochemically Generated ArIF2

DOI: 10.1021/acs.orglett.9b02884

Source and publish data:

Organic Letters (2019)

Update date:2022-08-04

Topics:

Authors:

Berger, Michael

Herszman, John D.

Waldvogel, Siegfried R.

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Article abstract of DOI:10.1021/acs.orglett.9b02884

A sustainable synthesis of 5-fluoromethyl-2-oxazoles by use of electrochemistry has been demonstrated. Hypervalent ArIF₂ is generated by direct electrochemical oxidation of iodoarene ArI in Et₃N·5HF and mediates the fluorocyclization

Full text of DOI:10.1021/acs.orglett.9b02884

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