Tetrahedron Asymmetry p. 2419 - 2422 (1993)
Update date:2022-08-03
Topics:
Uozumi, Yasuhiro
Kitayama, Kenji
Hayashi, Tamio
Hydrosilylation of styrenes bearing β-substituents with trichlorosilane was catalyzed by a palladium complex (0.1 mol percent) coordinated with (R)-2-methoxy-2'-diphenylphosphino-1,1'-binaphthyl ((R)-MeO-MOP) to give high yields of optically active 1-aryl-1-silylalkanes (80-85percent ee) as single regioisomers.The resulting silanes were readily converted into the corresponding optically active alcohols (80-99percent yield).
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