Tetrahedron Asymmetry p. 2419 - 2422 (1993)
Update date:2022-08-03
Topics:
Uozumi, Yasuhiro
Kitayama, Kenji
Hayashi, Tamio
Hydrosilylation of styrenes bearing β-substituents with trichlorosilane was catalyzed by a palladium complex (0.1 mol percent) coordinated with (R)-2-methoxy-2'-diphenylphosphino-1,1'-binaphthyl ((R)-MeO-MOP) to give high yields of optically active 1-aryl-1-silylalkanes (80-85percent ee) as single regioisomers.The resulting silanes were readily converted into the corresponding optically active alcohols (80-99percent yield).
View MoreZhejiang Kangfeng Chemical Co.,LTD.
Contact:+86-579-86709687
Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Contact:+86-574-89075960
Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
Contact:86-21-58226973
Address:No 351,Guoshoujing Road, Zhangjiang Hi-tech Park, Pudong, Shanghai, China
Zhengzhou Yuanli Biological Technology Co., Ltd.
Contact:+86-371-67897870/67897895
Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Nanjing Habo Medical Technology Co., Ltd.
Contact:025-85769882
Address:No.108. Ganjiabian east. Qixia District .Nanjing
Doi:10.1021/bi2005398
(2011)Doi:10.1016/j.tetlet.2014.09.113
(2014)Doi:10.1021/jp0028103
(2001)Doi:10.1021/ol0070379
(2001)Doi:10.1016/S0040-4020(00)01014-0
(2001)Doi:10.1021/acs.jmedchem.0c00961
(2020)