Tetrahedron Letters p. 3327 - 3330 (1998)
Update date:2022-08-03
Topics:
Blay, Gonzalo
Fernandez, Isabel
Formentin, Pilar
Pedro, Jose R.
Rosello, Antonio L.
Ruiz, Rafael
Journaux, Yves
The monomeric square-planar cobalt(III) complex of bis-N,N'- disubstituted oxamides catalyses the oxidative decarboxylation of α-hydroxy acids with molecular oxygen/pivalaldehyde with very good yields. This reaction offers an interesting alternative in the use of methyl mandelate as a convenient benzoyl anion equivalent.
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