Inorganic Chemistry p. 1544 - 1549 (1964)
Update date:2022-08-04
Topics:
Benner, Gereld S.
Hatfield, William E.
Meek, Devon W.
Chemical analyses, magnetic moments, electronic absorption spectra, and molar conductance values indicate that tris(3-dimethylarsinopropyl)phosphine (TAP) reacts with nickel(II) salts to form the five-coordinate cations [Ni(TAP)X]+ (where X is a monodentate anion). The aquo complex [Ni(TAP)H2O]2+ is analogous. The absorption spectra suggest that the cation has a trigonal-bipyramidal structure in which the organic molecule functions as a tetradentate ligand. The electronic absorption spectra and the chemical reactions of the complexes are discussed.
Xi'an Kaixiang Photoelectric Technology Co., Ltd
website:http://www.kxmaterials.com/
Contact:86-29-15991651477
Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
Suzhou Kangrun Pharmaceutical, Inc
Contact:86-512-63912376，63913329
Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Jurong Huaheng Natural Biological Products Factory
website:http://www.risebiochem.com
Contact:+86-13921007726
Address:Chuncheng town,Jurong city,Jiangsu province,China
Tianjin Pharmacn Medical Technology Co.,Ltd.
Contact:86-22-60122566ext.866(English),23359620
Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Contact:+86 021-51698675
Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
Doi:10.1002/adsc.201900286
(2019)Doi:10.1016/j.ejmech.2020.112216
(2020)Doi:10.1055/s-2001-11440
(2001)Doi:10.1021/ja01490a049
(1960)Doi:10.1002/hlca.19710540602
(1971)Doi:10.1016/0009-3084(71)90066-1
(1971)
