Inorganic Chemistry p. 1544 - 1549 (1964)
Update date:2022-08-04
Topics:
Benner, Gereld S.
Hatfield, William E.
Meek, Devon W.
Chemical analyses, magnetic moments, electronic absorption spectra, and molar conductance values indicate that tris(3-dimethylarsinopropyl)phosphine (TAP) reacts with nickel(II) salts to form the five-coordinate cations [Ni(TAP)X]+ (where X is a monodentate anion). The aquo complex [Ni(TAP)H2O]2+ is analogous. The absorption spectra suggest that the cation has a trigonal-bipyramidal structure in which the organic molecule functions as a tetradentate ligand. The electronic absorption spectra and the chemical reactions of the complexes are discussed.
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Doi:10.1002/adsc.201900286
(2019)Doi:10.1016/j.ejmech.2020.112216
(2020)Doi:10.1055/s-2001-11440
(2001)Doi:10.1021/ja01490a049
(1960)Doi:10.1002/hlca.19710540602
(1971)Doi:10.1016/0009-3084(71)90066-1
(1971)
