Carbonyl-Protected β-Lithio Aldehydes and Ketones via Reductive Lithiation. A General Preparative Method for Remarkably Versatile Homoenolate Equivalents

DOI: 10.1021/jo00027a004

Source and publish data:

Journal of Organic Chemistry p. 6 - 8 (1992)

Update date:2022-08-05

Topics: Reductive Lithiation

Authors:

Cherkauskas, John P.

Cohen, Theodore

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Article abstract of DOI:10.1021/jo00027a004

A general procedure for producing homoenolate equivalents consists of reductive lithiation, induced by 4,4'-di-tert-butylbiphenylide, of carbonyl-protected β-(phenylthio) carbonyl compounds prepared in turn by thiophenol addition to enones or the alkylati

Full text of DOI:10.1021/jo00027a004

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